I'm curious to know though - if concrete is more economical than bricks and mortar why don't we have more concrete houses built?And in my region, most houses built in at least the last 40 years have walls of concrete block. We build with concrete, just not by pouring it into walls.
Disclaimer, house building technologies vary wildly between different regions - but local to me, the catch is that almost all "bricks and mortar" houses are actually timber framed, with a brick veneer on the outside.
From the standpoint of CO2 emissions, the most important characteristic of [minerals used in Portland cement] is the calcium content. The calcium comes from calcium carbonate (limestone) and the first step of producing clinker is the decarbonation of the limestone:This is what the "37% clinker substitution" wedge of the "key levers for CO2 reduction" pie chart is referring to, from the china national building material group slide quoted in Ed Conway's thread.
CaCO3 ¡ú CaO + CO2
This is the chemical reaction that accounts for some 60% of CO2 emissions from the manufacture of traditional Portland cement. Since no large-volume concentrated sources of calcium exist other than limestone, the manufacture of calcium-based cements inevitably leads to substantial ¡°chemical¡± CO2 emissions associated solely with the decarbonation reaction, and not with the fuel burned in the process. It is exactly for this reason that the cement industry is such a significant CO2 emitter. This also a cause for optimism ¡ª it is clearly possible to reduce these emissions in a relatively inexpensive way, simply by changing the composition of cements.
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And that isn't even talking about the huge amount of CO2 from whatever fuel you burned to heat it up enough to drive the decomposition reaction forward in the first place. But if you somehow did the clinker step without using any fossil fuels (which feels unlikely because it takes a LOT of concentrated heat to do it, which would be quite challenging to do with pretty much anything besides fossil fuels), then you'd still have the emitted CO2 to deal with, which only gets reabsorbed into the concrete on an extremely long timeline. They touch on this by talking about how the Hoover Dam is still curing, and that's because there's still a whole lot of chemical potential energy residing there, each bit of which is attached to some bit of CO2 that had been driven off and which has not yet come back home to roost. So even if you made the clinker with 100% renewable energy, you'd still have CO2 that would need sequestering somehow if your mandate was truly zero-emissions on anything resembling a realistic timeline.
posted by notoriety public at 7:30 PM on September 16, 2021 [22 favorites]